EES 229
Invertebrate Paleontology
Spring 2004
return to
syllabus
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notes: 'Isotopes in
Paleoceanography'
Lab 6: Paleoceanography
Reading:
- Textbook Chapters 8 (p. 130-133), 9 (p.
149-152)
- Zachos, J. C., Pagani, M., Sloan, L.,
Thomas, E., and Billups, K., 2001. Trends, Rhythms and Aberrations
in Global Climate 65 Ma to Present. Science, vol. 292, p.
686-693
- Notes
on the use of oxygen and carbon isotope use in paleoceanography
(handout).
Goals of this lab: learn basic principles of
use of stable isotopes of carbon and oxygen in paleoceanography, as
well as basic climate development during the Cenozoic.
The lab consists of two parts:
- Microscope study of
material in the >63mm
size fraction.
- Interpretation of
isotope records.
Part 1:
1. The 4-well slide contains 4 samples: A,
B, C, and D. Two of these samples are Recent, two have a numerical
age of about 56 Ma; one of the Recent and one of the old samples is
from high latitudes; the other is from low latitudes. Use figure 2
from the reading (Science paper) to see how warm surface waters were
at that time at high latitudes (temperature of high latitude surface
waters is about the same as temperature of deep waters globally). Two
of the samples are from a high latitude (~65oS), two are
from within 4o of the equator. The most common objects in
each of the samples are planktonic foraminifera. Planktonic
foraminifera live in various latitudinal zones (see figure below for
Recent species, p. 151-152 text book) with higher diversity at lower
latitudes. Use the plate to determine which of the samples are
Recent, of which of these two is from high, which from low latitudes.
Define what objects other than planktonic foraminifera are present.
A and B are recent samples; A is
tropical, B from high latitudes. Specimens labeled 1, 2 as well as
3-5 are present in sample A. There are also radiolarians and
diatoms. In sample B there are only specimens as in 16-17
(different sides of same species), as well as terrigenous material
(large quartz grains), which fell from melting icebergs; there are
also radiolarians in this sample.
Planktonic foraminifera from the recent
oceans, arranged by latitudinal species assemblage. Plate from J. P.
Kennett, 1982, Marine Geology (Prentice-Hall), Figure
16-1.
2. Now determine which one of the remaining
samples is low and which one is from high latitude, assuming that the
diversity gradient (more species at low latitudes) was valid in the
past, but keeping in mind that the temperature gradients between high
and low latitudes were much smaller 56 Ma ago.
Sample C is the tropical sample,
with many specimens having specimens which are not rounded, but
have sharp edges and spines. Sample D is the sample from high
latitudes, dominated by rounded forms. Note the absence of
ice-rafted material in the polar sample, and the presence of more
variability in the planktonic foraminifera than in the modern
polar sample.
Part 2.
Use the notes
on on isotopes to answer the
following questions:
- Use the temperature equation to derive
the deep-water temperature of the average ocean at about 55 Ma
during the short peak in warmth, when d18O
reached values of about &endash;0.5 o/oo.
Assume that there was no ice, and use the appropriate oceanic
values of d18O
water (see notes
on on isotopes).
- t=16.9 - 4.38 (-0.5+1.26) + 0.10(-0.5
+ 1.26)2 = 13.6oC (this is very warm for
poles!)
- Now use that same equation (assuming no
polar ice caps) to calculate the temperature at about 33.5 Ma
(when d18Ocalcite
reached values of about +3.2 o/oo. First,
assume that there still were no ice caps to get the ocean water
values of d18O.
Is the temperature that you get realistic in view of the fact that
you just assumed that there were no ice caps? (remember that
deep-water ocean temperatures are equal to surface water
temperatures at the poles).
- t=16.9 -4.38 (3.2 + 1.26) + 0.10 (3.2
+ 1.26)2 = -0.6oC. This is a negative
temperature (freezing; although sea water is salt and still
liquid at this temperature). This result is thus inconsistent
with the assumption of 'no polar ice caps'.
- Then assume an oxygen isotope
composition as in the present oceans, and recalculate the
temperature of the deep waters.
- t=16.9 - 4.38 (3.2 + 0.28) + 0.10
(3.2 + 0.28)2 = 2.9oC.
- Present average deep-ocean temperatures
are close to 1-2oC. Does the temperature that you found
suggest that ice sheets at 33.5 Ma were similar in size to the
present ones or not?
- Found temperature is slightly on the
high side, but not very far off, in view of the various
uncertainties. Probably the polar ice sheet was slightly
smaller at that time.
- The carbon isotope composition of
benthic calcite is much lower than that of planktonic calcite (see
handout). Just after the extinction at the end of the Cretaceous,
however, this difference disappeared and the two groups of
organisms have almost the same value. What caused this?
- At the end of the Cretaceous oceanic
productivity collapsed, probably as a result of darkness after
a meteorite impact. Oceanic primary producers are mainly
microscopic algae with a very short life span, which die off
during a few months darkness. This change in carbon isotopes
thus most likely reflects the collapse of the biological pump
(thus major impact of all ocean life).
- What is the effect of fossil fuel
burning on the carbon isotopic composition of benthic and
planktonic foraminiferal shells?
- It wil add isotopically light carbon
(enriched in 12C) to the atmosphere, which then will
exchange this carbon with the dissolved inorganic carbon
reservoir in the oceans. This dissolved inorganic carbon then
will be used by plantkonic as well as benthic foraminifera:
isotopically light carbon has been added to the complete
oceanic reservoir.
- During the very warm period about 55 Ma
ago, there was a very rapid shift (over less than about 1000
years) to lower carbon isotope values in planktonic and benthic
foraminifera worldwide. Could such a rapid change have been caused
by a change in productivity in the oceans?
- No; changes in productivity will
affect the gradient between planktonic and benthic forms, not
both. Such an overall change must have been caused by addition
of isotopically light carbon to the ocean-atmosphere system. In
this specific case, the isotope effect is so large that even
complete burning of all the world's life would not be enough!
Much speculation on this event (with implications for future
global warming) is ongoing (click here
for more information).